
Sulfide Contamination
#1
Posted 16 October 2003 - 07:52 PM
Thomas
#2
Posted 17 October 2003 - 01:56 PM
you could try adding a 1% of sodium bicarbonate to neutralise the sulphuric acid that is formed (don't know how reliable this is)
the only other option i can think of is to try and obtain a higher grade of chemicals but this will cost a lot more

#3
Posted 17 October 2003 - 09:24 PM
I think I remember reading somewhere that barium and strontium carbonates from ceramic supply shops are contaminated with a trace of the corresponding sulfide from the manufacturing process. If this were true, then it would be dangerous to use potassium chlorate with it. Does anyone know whether there is such a contamination (I've tried to do some reasearch on it, but nothing has come up yet).
Thomas
The supply in Ceramic shops is Technical grade. The contamination is very small and should not generally be a problem. Of course, Barium Chlorate is a very sensitive chemical. If you have to use chlorates I would suggest using mixtures of potassium Chlorate with Barium Nitrate. Those are much safer and generally produce wonderful results.
BigG
#4
Posted 18 October 2003 - 03:26 PM
#5
Posted 18 October 2003 - 05:22 PM
Without a clorine donor like parlon or pvc you will get a green color.
But yes if you want an realy deep green color it is advisable to use either of these two donor's preferably parlon.
The only problem is offcourse where to get it, as far as I know parlon can only be bought at special pyrochemical stores like skylighter

Edited by Jerronimo, 18 October 2003 - 05:23 PM.
#6
Posted 20 October 2003 - 10:05 PM
This is one chimical you can ship with no problem. Just order it from skylighter.Hey lord dranack,
Without a clorine donor like parlon or pvc you will get a green color.
But yes if you want an realy deep green color it is advisable to use either of these two donor's preferably parlon.
The only problem is offcourse where to get it, as far as I know parlon can only be bought at special pyrochemical stores like skylighter.
BigG
#7
Posted 21 October 2003 - 12:13 PM
What I have noticed is that if you opt for non-air shipping the costs are cheaper when the weight goes up - possibility of a few of us clubbibg together??
I've tried everywhere to get parlon or PVC but it seems really hard to get. PVC is used as a hot-dip powder coating, but it's not the most common one. I'm sure this material will work but none of the coating suppliers I've talked to stock it.
I have had success 'powdering my own' (PVC conduit), but it's hard to do as the MP is low and power tools tend to make it soften and stick together...

#8
Posted 21 October 2003 - 04:43 PM
Stuart
#9
Posted 21 October 2003 - 05:18 PM

As for strontium/bariumcarbonate, I think you will find it in most ceramic suplies shops.
#10
Posted 23 October 2003 - 11:31 AM
They can supply Strontium carbonate, copper oxide, bentonite and all sorts of other goodies...
ctm
Don't tell them what you want it for though!

#11
Posted 23 October 2003 - 03:31 PM

Bit of sarcasm there. Thanks for the link Phil.
Stuart
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